Saprc07tb ae6 v5.1 mech.def

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Information is taken directly from the mech.def file.

  • Fall-off/pressure dependent reaction rate constants ([M] equals air number density):
    • For rate constants with ko, kinf, n, F values: k = [ k0[M]/(1+k0[M]/kinf)]FG, where G=1/[1+(log(k0[M]/kinf)/n)-2)]
    • For rate constants with k1, k2: k = k1 + k2 [M]
    • For rate constants with k0, k2, k3: k = k0 + k3[M]/(1+k3[M]/k2)
    • For rate constants with k1, k2, k3: k = k1 + k2[M] + k3
  • For rate constants with the form A/<PHOT>, k equals A times the photolysis rates, PHOT.
  • For rate constants with the form A~<HETERO>, k equals A times the heterogeneous rate constant, HETERO.
  • For rate constants with the form A*K<RCONST>, k equals A times the previously defined rate constant, RCONST.
  • For rate constants with the form A~<HETERO>, k equals A times the heterogeneous rate constant, HETERO.
  • For rate constants with the form A?<OPERATOR>, k equals A times an , OPERATOR. For saprc07tb_ae6_aq, the operators are
    • RO2NO = K<BR07>*[NO]
    • RO2HO2 = K<BR08>*[HO2]
    • RO2NO3 = K<BR09>*[NO3]
    • RO2RO2 = K<BR10>*[MEO2] + K<BR11>*[RO2C] + K<BR11>*[RO2XC]
    • RO2RO3 = K<BR25>*[MECO3] + K<BR25>*[RCO3] + K<BR25>*[BZCO3] + <BR25>*[MACO3]
    • RO2RO = RO2NO + RO2NO3 + RO2RO3 + 0.5*RO2RO2
    • RO2XRO = RO2HO2 + 0.5*RO2RO2
    • RO2RO2M = 0.5*RO2RO2
    • RO22NN = RO2NO3 + RO2RO3 + 0.5*RO2RO2

where [species] equals the concentration of a mechanism species at the beginning of the integration time-step for the chemistry's numerical solver.

Check the species table for the reactants and products used the below reactions.

Label Reaction Rate Const Notes Reference
<1> NO2 = NO + O3P 1.0/<NO2_06>
<2> O3P + O2 + M = O3 5.68e-34*(T/300)(-2.60)
<3> O3P + O3 = 8.00e-12*exp(-2060/T)
<4> O3P + NO = NO2 k0=9.00e-32*(T/300)(-1.50), kinf=3.00e-11, F=0.60, n=1.0
<5> O3P + NO2 = NO 5.50e-12*exp(188/T)
<6> O3P + NO2 = NO3 k0=2.50e-31*(T/300)(-1.80), kinf=2.20e-11*(T/300)(-0.70), F=0.60, n=1.0
<7> O3 + NO = NO2 3.00e-12*exp(-1500/T)
<8> O3 + NO2 = NO3 1.40e-13*exp(-2470/T)
<9> NO + NO3 = 2*NO2 1.80e-11*exp(110/T)
<10> NO + NO + O2 = 2*NO2 3.30e-39*exp(530/T)
<11> NO2 + NO3 = N2O5 k0=3.60e-30*(T/300)(-4.10), kinf=1.90e-12*(T/300)(0.20), F=0.35, n=1.33
<12> N2O5 = NO2 + NO3 k0=1.30e-03*(T/300)(-3.50)*exp(-11000/T), kinf=9.70e14*(T/300)(0.10)*exp(-11080/T), F=0.35, n=1.33
<13> N2O5 + H2O = 2*HNO3 1.00e-22
<14> N2O5 + H2O + H2O = 2*HNO3 0.00e00
<15> NO2 + NO3 = NO + NO2 4.50e-14*exp(-1260/T)
<16> NO3 = NO 1.0/<NO3NO_06>
<17> NO3 = NO2 + O3P 1.0/<NO3NO2_6>
<18> O3 = O1D 1.0/<O3O1D_06>
<19> O3 = O3P 1.0/<O3O3P_06>
<20> O1D + H2O = 2*OH 1.63e-10*exp(60/T)
<21> O1D + M = O3P 2.38e-11*exp(96/T)
<22> OH + NO = HONO k0=7.00e-31*(T/300)(-2.60), kinf=3.60e-11*(T/300)(-0.10), F=0.60, n=1.0
<23> HONO = OH + NO 1.0/<HONO_06>
<24> OH + HONO = NO2 2.50e-12*exp(260/T)
<25> OH + NO2 = HNO3 k0=3.2e-30*(T/300)(-4.50), kinf=3.0e-11, F=0.41, n=1.24
<26> OH + NO3 = HO2 + NO2 2.00e-11
<27> OH + HNO3 = NO3 k0=2.40e-14*exp(460/T), k2=2.70e-17*exp(2199/T), k3=6.50e-34*exp(1335/T)
<28> HNO3 = OH + NO2 1.0/<HNO3>
<29> OH + CO = HO2 + CO2 k1=1.44e-13*exp(-0/T), k2=3.43e-33*exp(-0/T)
<30> OH + O3 = HO2 1.70e-12*exp(-940/T)
<31> HO2 + NO = OH + NO2 3.60e-12*exp(270/T)
<32> HO2 + NO2 = HNO4 k0=2.00e-31*(T/300)(-3.40), kinf=2.90e-12*(T/300)(-1.10), F=0.60, n=1.0
<33> HNO4 = HO2 + NO2 k0=3.72e-05*(T/300)(-2.40)*exp(-10650/T), kinf=5.42e15*(T/300)(-2.30)*exp(-11170/T), F=0.60, n=1.0
<34> HNO4 = 0.61*HO2 + 0.61*NO2 + 0.39*OH + 0.39*NO3 1.0/<HNO4_06>
<35> HNO4 + OH = NO2 1.30e-12*exp(380/T)
<36> HO2 + O3 = OH 2.03e-16*(T/300)(4.57)*exp(693/T)
<37> HO2 + HO2 = HO2H k1=2.20e-13*exp(600/T), k2=1.90e-33*exp(980/T)
<38> HO2 + HO2 + H2O = HO2H k1=3.08e-34*exp(2800/T), k2=2.66e-54*exp(3180/T)
<39> NO3 + HO2 = 0.8*OH + 0.8*NO2 + 0.2*HNO3 4.00e-12
<40> NO3 + NO3 = 2*NO2 8.50e-13*exp(-2450/T)
<41> HO2H = 2*OH 1.0/<H2O2>
<42> HO2H + OH = HO2 1.80e-12
<43> OH + HO2 = 4.80e-11*exp(250/T)
<44> OH + SO2 = HO2 + SULF + SULRXN k0=3.30e-31*(T/300)(-4.30), kinf=1.60e-12, F=0.60, n=1.0
<45> OH + H2 = HO2 7.70e-12*exp(-2100/T)
<BR01> MEO2 + NO = NO2 + HCHO + HO2 2.30e-12*exp(360/T)
<BR02> MEO2 + HO2 = COOH 3.46e-13*(T/300)(0.36)*exp(780/T)
<BR03> MEO2 + HO2 = HCHO 3.34e-14*(T/300)(-3.53)*exp(780/T)
<BR04> MEO2 + NO3 = HCHO + HO2 + NO2 1.30e-12
<BR05> MEO2 + MEO2 = MEOH + HCHO 6.39e-14*(T/300)(-1.80)*exp(365/T)
<BR06> MEO2 + MEO2 = 2*HCHO + 2*HO2 7.40e-13*exp(-520/T)
<BR07> RO2C + NO = NO2 2.60e-12*exp(380/T)
<BR08> RO2C + HO2 = 3.80e-13*exp(900/T)
<BR09> RO2C + NO3 = NO2 2.30e-12
<BR10> RO2C + MEO2 = 0.5*HO2 + 0.75*HCHO + 0.25*MEOH 2.00e-13
<BR11> RO2C + RO2C = 3.50e-14
<BR12> RO2XC + NO = XN 1.0*K<BR07>
<BR13> RO2XC + HO2 = 1.0*K<BR08>
<BR14> RO2XC + NO3 = NO2 1.0*K<BR09>
<BR15> RO2XC + MEO2 = 0.5*HO2 + 0.75*HCHO + 0.25*MEOH 1.0*K<BR10>
<BR16> RO2XC + RO2C = 1.0*K<BR11>
<BR17> RO2XC + RO2XC = 1.0*K<BR11>
<BR18> MECO3 + NO2 = PAN k0=2.70e-28*(T/300)(-7.10), kinf=1.21e-11*(T/300)(-0.90), F=0.30, n=1.41
<BR19> PAN = MECO3 + NO2 k0=4.90e-03*exp(-12100/T), kinf=4.00e16*exp(-13600/T), F=0.30, n=1.41
<BR20> PAN = 0.6*MECO3 + 0.6*NO2 + 0.4*MEO2 + 0.4*CO2 + 0.4*NO3 1.0/<PAN>
<BR21> MECO3 + NO = MEO2 + CO2 + NO2 7.50e-12*exp(290/T)
<BR22> MECO3 + HO2 = 0.105*CCOOOH + 0.045*CCOOH + 0.15*O3 + 0.44*OH + 0.44*MEO2 + 0.44*CO2 5.20e-13*exp(980/T)
<BR23> MECO3 + NO3 = MEO2 + CO2 + NO2 1.0*K<BR09>
<BR24> MECO3 + MEO2 = 0.1*CCOOH + 0.1*HCHO + 0.9*HCHO + 0.9*HO2 + 0.9*MEO2 + 0.9*CO2 2.00e-12*exp(500/T)
<BR25> MECO3 + RO2C = MEO2 + CO2 4.40e-13*exp(1070/T)
<BR26> MECO3 + RO2XC = MEO2 + CO2 1.0*K<BR25>
<BR27> MECO3 + MECO3 = 2*MEO2 + 2*CO2 2.90e-12*exp(500/T)
<BR28> RCO3 + NO2 = PAN2 1.21e-11*(T/300)(-1.07)*exp(-0/T)
<BR29> PAN2 = RCO3 + NO2 8.30e16*exp(-13940/T)
<BR30> PAN2 = 0.6*RCO3 + 0.6*NO2 + 0.4*RO2C + 0.4*xHO2 + 0.4*yROOH + 0.4*xCCHO + 0.4*CO2 + 0.4*NO3 1.0/<PAN>
<BR31> RCO3 + NO = NO2 + RO2C + xHO2 + yROOH + xCCHO + CO2 6.70e-12*exp(340/T)
<BR32> RCO3 + HO2 = 0.3075*RCOOOH + .1025*RCOOH + 0.15*O3 + 0.44*OH + 0.44*xHO2 + 0.44*RO2C + 0.44*CO2 + 0.44*xCCHO + 0.44*yROOH 1.0*K<BR22>
<BR33> RCO3 + NO3 = NO2 + RO2C + xHO2 + yROOH + xCCHO + CO2 1.0*K<BR09>
<BR34> RCO3 + MEO2 = HCHO + HO2 + RO2C + xHO2 + xCCHO + yROOH + CO2 1.0*K<BR24>
<BR35> RCO3 + RO2C = RO2C + xHO2 + xCCHO + yROOH + CO2 1.0*K<BR25>
<BR36> RCO3 + RO2XC = RO2C + xHO2 + xCCHO + yROOH + CO2 1.0*K<BR25>
<BR37> RCO3 + MECO3 = 2*CO2 + MEO2 + RO2C + xHO2 + yROOH + xCCHO 1.0*K<BR27>
<BR38> RCO3 + RCO3 = 2*RO2C + 2*xHO2 + 2*xCCHO + 2*yROOH + 2*CO2 1.0*K<BR27>
<BR39> BZCO3 + NO2 = PBZN 1.37e-11
<BR40> PBZN = BZCO3 + NO2 7.90e16*exp(-14000/T)
<BR41> PBZN = 0.6*BZCO3 + 0.6*NO2 + 0.4*CO2 + 0.4*BZO + 0.4*RO2C + 0.4*NO3 1.0/<PAN>
<BR42> BZCO3 + NO = NO2 + CO2 + BZO + RO2C 1.0*K<BR31>
<BR43> BZCO3 + HO2 = .3075*RCOOOH + 0.1025*RCOOH + 0.15*O3 + 0.44*OH + 0.44*BZO + 0.44*RO2C + 0.44*CO2 1.0*K<BR22>
<BR44> BZCO3 + NO3 = NO2 + CO2 + BZO + RO2C 1.0*K<BR09>
<BR45> BZCO3 + MEO2 = HCHO + HO2 + RO2C + BZO + CO2 1.0*K<BR24>
<BR46> BZCO3 + RO2C = RO2C + BZO + CO2 1.0*K<BR25>
<BR47> BZCO3 + RO2XC = RO2C + BZO + CO2 1.0*K<BR25>
<BR48> BZCO3 + MECO3 = 2*CO2 + MEO2 + BZO + RO2C 1.0*K<BR27>
<BR49> BZCO3 + RCO3 = 2*CO2 + RO2C + xHO2 + yROOH + xCCHO + BZO + RO2C 1.0*K<BR27>
<BR50> BZCO3 + BZCO3 = 2*BZO + 2*RO2C + 2*CO2 1.0*K<BR27>
<BR51> MACO3 + NO2 = MAPAN 1.0*K<BR28>
<BR52> MAPAN = MACO3 + NO2 1.60e16*exp(-13486/T)
<BR53> MAPAN = 0.6*MACO3 + 0.6*NO2 + 0.4*CO2 + 0.4*HCHO + 0.4*MECO3 + 0.4*NO3 1.0/<PAN>
<BR54> MACO3 + NO = NO2 + CO2 + HCHO + MECO3 1.0*K<BR31>
<BR55> MACO3 + HO2 = 0.3075*RCOOOH + 0.1025*RCOOH + 0.15*O3 + 0.44*OH + 0.44*HCHO + 0.44*MECO3 + 0.44*CO2 1.0*K<BR22>
<BR56> MACO3 + NO3 = NO2 + CO2 + HCHO + MECO3 1.0*K<BR09>
<BR57> MACO3 + MEO2 = 2*HCHO + HO2 + CO2 + MECO3 1.0*K<BR24>
<BR58> MACO3 + RO2C = CO2 + HCHO + MECO3 1.0*K<BR25>
<BR59> MACO3 + RO2XC = CO2 + HCHO + MECO3 1.0*K<BR25>
<BR60> MACO3 + MECO3 = 2*CO2 + MEO2 + HCHO + MECO3 1.0*K<BR27>
<BR61> MACO3 + RCO3 = HCHO + MECO3 + RO2C + xHO2 + yROOH + xCCHO + 2*CO2 1.0*K<BR27>
<BR62> MACO3 + BZCO3 = HCHO + MECO3 + BZO + RO2C + 2*CO2 1.0*K<BR27>
<BR63> MACO3 + MACO3 = 2*HCHO + 2*MECO3 + 2*CO2 1.0*K<BR27>
<BR64> TBUO + NO2 = RNO3-2*XC 2.40e-11
<BR65> TBUO = ACETONE + MEO2 7.50e14*exp(-8152/T)
<BR66> BZO + NO2 = NPHE 2.30e-11*exp(150/T)
<BR67> BZO + HO2 = CRES-1*XC 1.0*K<BR08>
<BR68> BZO = CRES + RO2C + xHO2-1*XC 1.00e-03
<RO01> xHO2 = HO2 1.0?RO2RO
<RO02> xHO2 = 1.0?RO2XRO
<RO03> xOH = OH 1.0?RO2RO
<RO04> xOH = 1.0?RO2XRO
<RO05> xNO2 = NO2 1.0?RO2RO
<RO06> xNO2 = XN 1.0?RO2XRO
<RO07> xMEO2 = MEO2 1.0?RO2RO
<RO08> xMEO2 = XC 1.0?RO2XRO
<RO09> xMECO3 = MECO3 1.0?RO2RO
<RO10> xMECO3 = 2*XC 1.0?RO2XRO
<RO11> xRCO3 = RCO3 1.0?RO2RO
<RO12> xRCO3 = 3*XC 1.0?RO2XRO
<RO13> xMACO3 = MACO3 1.0?RO2RO
<RO14> xMACO3 = 4*XC 1.0?RO2XRO
<RO15> xTBUO = TBUO 1.0?RO2RO
<RO16> xTBUO = 4*XC 1.0?RO2XRO
<RO17> xCO = CO 1.0?RO2RO
<RO18> xCO = XC 1.0?RO2XRO
<BP01> HCHO = 2*HO2 + CO 1.0/<HCHOR_06>
<BP02> HCHO = CO 1.0/<HCHOM_06>
<BP03> HCHO + OH = HO2 + CO 5.40e-12*exp(135/T)
<BP07> HCHO + NO3 = HNO3 + HO2 + CO 2.00e-12*exp(-2431/T)
<BP08> CCHO + OH = MECO3 4.40e-12*exp(365/T)
<BP09> CCHO = CO + HO2 + MEO2 1.0/<CCHO_R>
<BP10> CCHO + NO3 = HNO3 + MECO3 1.40e-12*exp(-1860/T)
<BP11> RCHO + OH = 0.965*RCO3 + 0.035*RO2C + 0.035*xHO2 + 0.035*xCO + 0.035*xCCHO + 0.035*yROOH 5.10e-12*exp(405/T)
<BP12> RCHO = RO2C + xHO2 + yROOH + xCCHO + CO + HO2 1.0/<C2CHO>
<BP13> RCHO + NO3 = HNO3 + RCO3 1.40e-12*exp(-1601/T)
<BP14> ACETONE + OH = RO2C + xMECO3 + xHCHO + yROOH 4.56e-14*(T/300)(3.65)*exp(429/T)
<BP15> ACETONE = 0.62*MECO3 + 1.38*MEO2 + 0.38*CO 5.00e-1/<ACET_06>
<BP16> MEK + OH = 0.967*RO2C + 0.039*RO2XC + 0.039*zRNO3 + 0.376*xHO2 + 0.51*xMECO3 + 0.074*xRCO3 + 0.088*xHCHO + 0.504*xCCHO + 0.376*xRCHO + yROOH + 0.3*XC 1.30e-12*(T/300)(2.00)*exp(-25/T)
<BP17> MEK = MECO3 + RO2C + xHO2 + xCCHO + yROOH 1.75e-1/<MEK_06>
<BP18> MEOH + OH = HCHO + HO2 2.85e-12*exp(-345/T)
<BP19> HCOOH + OH = HO2 + CO2 4.50e-13
<BP20> CCOOH + OH = 0.509*MEO2 + 0.491*RO2C + 0.509*CO2 + 0.491*xHO2 + 0.491*xMGLY + 0.491*yROOH-0.491*XC 4.20e-14*exp(855/T)
<BP21> RCOOH + OH = RO2C + xHO2 + 0.143*CO2 + 0.142*xCCHO + 0.4*xRCHO + 0.457*xBACL + yROOH-0.455*XC 1.20e-12
<BP22> COOH + OH = 0.3*HCHO + 0.3*OH + 0.7*MEO2 3.80e-12*exp(200/T)
<BP23> COOH = HCHO + HO2 + OH 1.0/<COOH>
<BP24> ROOH + OH = 0.744*OH + 0.251*RO2C + 0.004*RO2XC + 0.004*zRNO3 + 0.744*RCHO + 0.239*xHO2 + 0.012*xOH + 0.012*xHCHO + 0.012*xCCHO + 0.205*xRCHO + 0.034*xPROD2 + 0.256*yROOH-0.115*XC 2.50e-11
<BP25> ROOH = RCHO + HO2 + OH 1.0/<COOH>
<BP26> R6OOH + OH = 0.84*OH + 0.222*RO2C + 0.029*RO2XC + 0.029*zRNO3 + 0.84*PRD2 + 0.09*xHO2 + 0.041*xOH + 0.02*xCCHO + 0.075*xRCHO + 0.084*xPROD2 + 0.16*yROOH + 0.02*XC 5.60e-11
<BP27> R6OOH = OH + 0.142*HO2 + 0.782*RO2C + 0.077*RO2XC + 0.077*zRNO3 + 0.085*RCHO + 0.142*PRD2 + 0.782*xHO2 + 0.026*xCCHO + 0.058*xRCHO + 0.698*xPROD2 + 0.858*yR6OOH + 0.017*XC 1.0/<COOH>
<BP28> RAOOH + OH = 0.139*OH + 0.148*HO2 + 0.589*RO2C + 0.124*RO2XC + 0.124*zRNO3 + 0.074*PRD2 + 0.147*MGLY + 0.139*IPRD + 0.565*xHO2 + 0.024*xOH + 0.448*xRCHO + 0.026*xGLY + 0.03*xMEK + 0.252*xMGLY + 0.073*xAFG1 + 0.073*xAFG2 + 0.713*yR6OOH + 2.674*XC 1.41e-10
<BP29> RAOOH = OH + HO2 + 0.5*GLY + 0.5*MGLY + 0.5*AFG1 + 0.5*AFG2 + 0.5*XC 1.0/<COOH>
<BP30> GLY = 2*CO + 2*HO2 1.0/<GLY_07R>
<BP31> GLY = HCHO + CO 1.0/<GLY_07M>
<BP32> GLY + OH = 0.70*HO2 + 1.40*CO + 0.3*HCOCO3 3.10e-12*exp(342.2/T)
<BP33> GLY + NO3 = HNO3 + 0.70*HO2 + 1.40*CO + 0.3*HCOCO3 2.80e-12*exp(-2390/T)
<BP34> MGLY = HO2 + CO + MECO3 1.0/<MGLY_06>
<BP35> MGLY + OH = CO + MECO3 1.50e-11
<BP36> MGLY + NO3 = HNO3 + CO + MECO3 1.40e-12*exp(-1895/T)
<BP37> BACL = 2*MECO3 1.0/<BACL_07>
<BP38> CRES + OH = 0.2*BZO + 0.8*RO2C + 0.8*xHO2 + 0.8*yR6OOH + 0.25*xMGLY + 5.05*XC 1.70e-12*exp(950/T)
<BP39> CRES + NO3 = HNO3 + BZO + XC 1.40e-11
<BP40> NPHE + OH = BZO + XN 3.50e-12
<BP41> NPHE = HONO + 6*XC 1.50e-3/<NO2_06>
<BP42> NPHE = 6*XC + XN 1.50e-2/<NO2_06>
<BP43> BALD + OH = BZCO3 1.20e-11
<BP44> BALD = 7*XC 6.00e-2/<BALD_06>
<BP45> BALD + NO3 = HNO3 + BZCO3 1.34e-12*exp(-1860/T)
<BP46> AFG1 + OH = 0.217*MACO3 + 0.723*RO2C + 0.06*RO2XC + 0.06*zRNO3 + 0.521*xHO2 + 0.201*xMECO3 + 0.334*xCO + 0.407*xRCHO + 0.129*xMEK + 0.107*xGLY + 0.267*xMGLY + 0.783*yR6OOH + 0.284*XC 7.40e-11
<BP47> AFG1 + O3 = 0.826*OH + 0.522*HO2 + 0.652*RO2C + 0.522*CO + 0.174*CO2 + 0.432*GLY + 0.568*MGLY + 0.652*xRCO3 + 0.652*xHCHO + 0.652*yR6OOH-0.872*XC 9.66e-18
<BP48> AFG1 = 1.023*HO2 + 0.173*MEO2 + 0.305*MECO3 + 0.5*MACO3 + 0.695*CO + 0.195*GLY + 0.305*MGLY + 0.217*XC 1.0/<AFG1>
<BP49> AFG2 + OH = 0.217*MACO3 + 0.723*RO2C + 0.06*RO2XC + 0.06*zRNO3 + 0.521*xHO2 + 0.201*xMECO3 + 0.334*xCO + 0.407*xRCHO + 0.129*xMEK + 0.107*xGLY + 0.267*xMGLY + 0.783*yR6OOH + 0.284*XC 7.40e-11
<BP50> AFG2 + O3 = 0.826*OH + 0.522*HO2 + 0.652*RO2C + 0.522*CO + 0.174*CO2 + 0.432*GLY + 0.568*MGLY + 0.652*xRCO3 + 0.652*xHCHO + 0.652*yR6OOH-0.872*XC 9.66e-18
<BP51> AFG2 = PRD2-1*XC 1.0/<AFG1>
<BP52> AFG3 + OH = 0.206*MACO3 + 0.733*RO2C + 0.117*RO2XC + 0.117*zRNO3 + 0.561*xHO2 + 0.117*xMECO3 + 0.114*xCO + 0.274*xGLY + 0.153*xMGLY + 0.019*xBACL + 0.195*xAFG1 + 0.195*xAFG2 + 0.231*xIPRD + 0.794*yR6OOH + 0.938*XC 9.35e-11
<BP53> AFG3 + O3 = 0.471*OH + 0.554*HO2 + 0.013*MECO3 + 0.258*RO2C + 0.007*RO2XC + 0.007*zRNO3 + 0.58*CO + 0.19*CO2 + 0.366*GLY + 0.184*MGLY + 0.35*AFG1 + 0.35*AFG2 + 0.139*AFG3 + 0.003*MACR + 0.004*MVK + 0.003*IPRD + 0.095*xHO2 + 0.163*xRCO3 + 0.163*xHCHO + 0.095*xMGLY + 0.264*yR6OOH-0.575*XC 1.43e-17
<BP54> MACR + OH = 0.5*MACO3 + 0.5*RO2C + 0.5*xHO2 + 0.416*xCO + 0.084*xHCHO + 0.416*xMEK + 0.084*xMGLY + 0.5*yROOH-0.416*XC 8.00e-12*exp(380/T)
<BP55> MACR + O3 = 0.208*OH + 0.108*HO2 + 0.1*RO2C + 0.45*CO + 0.117*CO2 + 0.1*HCHO + 0.9*MGLY + 0.333*HCOOH + 0.1*xRCO3 + 0.1*xHCHO + 0.1*yROOH-0.1*XC 1.40e-15*exp(-2100/T)
<BP56> MACR + NO3 = 0.5*MACO3 + 0.5*RO2C + 0.5*HNO3 + 0.5*xHO2 + 0.5*xCO + 0.5*yROOH + 1.5*XC + 0.5*XN 1.50e-12*exp(-1815/T)
<BP57> MACR + O3P = RCHO + XC 6.34e-12
<BP58> MACR = 0.33*OH + 0.67*HO2 + 0.34*MECO3 + 0.33*MACO3 + 0.33*RO2C + 0.67*CO + 0.34*HCHO + 0.33*xMECO3 + 0.33*xHCHO + 0.33*yROOH 1.0/<MACR_06>
<BP59> MVK + OH = 0.975*RO2C + 0.025*RO2XC + 0.025*zRNO3 + 0.3*xHO2 + 0.675*xMECO3 + 0.3*xHCHO + 0.675*xHOCCHO + 0.3*xMGLY + yROOH-0.05*XC 2.60e-12*exp(610/T)
<BP60> MVK + O3 = 0.164*OH + 0.064*HO2 + 0.05*RO2C + 0.05*xHO2 + 0.475*CO + 0.124*CO2 + 0.05*HCHO + 0.95*MGLY + 0.351*HCOOH + 0.05*xRCO3 + 0.05*xHCHO + 0.05*yROOH-0.05*XC 8.50e-16*exp(-1520/T)
<BP62> MVK + O3P = 0.45*RCHO + 0.55*MEK + 0.45*XC 4.32e-12
<BP63> MVK = 0.4*MEO2 + 0.6*CO + 0.6*PRD2 + 0.4*MACO3-2.2*XC 1.0/<MVK_06>
<BP64> IPRD + OH = 0.289*MACO3 + 0.67*RO2C + 0.67*xHO2 + 0.041*RO2XC + 0.041*zRNO3 + 0.336*xCO + 0.055*xHCHO + 0.129*xHOCCHO + 0.013*xRCHO + 0.15*xMEK + 0.332*xPROD2 + 0.15*xGLY + 0.174*xMGLY-0.504*XC + 0.711*yR6OOH 6.19e-11
<BP65> IPRD + O3 = 0.285*OH + 0.4*HO2 + 0.048*RO2C + 0.048*xRCO3 + 0.498*CO + 0.14*CO2 + 0.124*HCHO + 0.21*MEK + 0.023*GLY + 0.742*MGLY + 0.1*HCOOH + 0.372*RCOOH + 0.047*xHOCCHO + 0.001*xHCHO + 0.048*yR6OOH-0.329*XC 4.18e-18
<BP66> IPRD + NO3 = 0.15*MACO3 + 0.15*HNO3 + 0.799*RO2C + 0.799*xHO2 + 0.051*RO2XC + 0.051*zRNO3 + 0.572*xCO + 0.227*xHCHO + 0.218*xRCHO + 0.008*xMGLY + 0.572*xRNO3 + 0.85*yR6OOH + 0.278*XN-0.815*XC 1.00e-13
<BP67> IPRD = 1.233*HO2 + 0.467*MECO3 + 0.3*RCO3 + 1.233*CO + 0.3*HCHO + 0.467*HOCCHO + 0.233*MEK-0.233*XC 1.0/<MACR_06>
<BP68> PRD2 + OH = 0.472*HO2 + 0.379*xHO2 + 0.029*xMECO3 + 0.049*xRCO3 + 0.473*RO2C + 0.071*RO2XC + 0.071*zRNO3 + 0.002*HCHO + 0.211*xHCHO + 0.001*CCHO + 0.083*xCCHO + 0.143*RCHO + 0.402*xRCHO + 0.115*xMEK + 0.329*PRD2 + 0.007*xPROD2 + 0.528*yR6OOH + 0.877*XC 1.55e-11
<BP69> PRD2 = 0.913*xHO2 + 0.4*MECO3 + 0.6*RCO3 + 1.59*RO2C + 0.087*RO2XC + 0.087*zRNO3 + 0.303*xHCHO + 0.163*xCCHO + 0.78*xRCHO + yR6OOH-0.091*XC 4.86e-3/<MEK_06>
<BP70> RNO3 + OH = 0.189*HO2 + 0.305*xHO2 + 0.019*NO2 + 0.313*xNO2 + 0.976*RO2C + 0.175*RO2XC + 0.175*zRNO3 + 0.011*xHCHO + 0.429*xCCHO + 0.001*RCHO + 0.036*xRCHO + 0.004*xACETONE + 0.01*MEK + 0.17*xMEK + 0.008*PRD2 + 0.031*xPROD2 + 0.189*RNO3 + 0.305*xRNO3 + 0.157*yROOH + 0.636*yR6OOH + 0.174*XN + 0.04*XC 7.20e-12
<BP71> RNO3 = 0.344*HO2 + 0.554*xHO2 + NO2 + 0.721*RO2C + 0.102*RO2XC + 0.102*zRNO3 + 0.074*HCHO + 0.061*xHCHO + 0.214*CCHO + 0.23*xCCHO + 0.074*RCHO + 0.063*xRCHO + 0.008*xACETONE + 0.124*MEK + 0.083*xMEK + 0.19*PRD2 + 0.261*xPROD2 + 0.066*yROOH + 0.591*yR6OOH + 0.396*XC 1.0/<IC3ONO2>
<BP72> HOCCHO + OH = MECO3 1.0*K<BP08>
<BP73> HOCCHO = CO + 2*HO2 + HCHO 1.0/<HOCCHO_IUPAC>
<BP74> HOCCHO + NO3 = HNO3 + MECO3 1.0*K<BP10>
<BP75> ACROLEIN + OH = 0.25*xHO2 + 0.75*MACO3 + 0.25*RO2C + 0.167*xCO + 0.083*xHCHO + 0.167*xCCHO + 0.083*xGLY + 0.25*yROOH-0.75*XC 1.99e-11
<BP76> ACROLEIN + O3 = 0.83*HO2 + 0.33*OH + 1.005*CO + 0.31*CO2 + 0.5*HCHO + 0.185*HCOOH + 0.5*GLY 1.40e-15*exp(-2528/T)
<BP77> ACROLEIN + NO3 = 0.031*xHO2 + 0.967*MACO3 + 0.031*RO2C + 0.002*RO2XC + 0.002*zRNO3 + 0.967*HNO3 + 0.031*xCO + 0.031*xRNO3 + 0.033*yROOH + 0.002*XN-1.097*XC 1.18e-15
<BP78> ACROLEIN + O3P = RCHO 2.37e-12
<BP79> ACROLEIN = 1.066*HO2 + 0.178*OH + 0.234*MEO2 + 0.33*MACO3 + 1.188*CO + 0.102*CO2 + 0.34*HCHO + 0.05*CCOOH-0.284*XC 1.0/<ACRO_09>
<BP80> CCOOOH + OH = 0.98*MECO3 + 0.02*RO2C + 0.02*CO2 + 0.02*xOH + 0.02*xHCHO + 0.02*yROOH 5.28e-12
<BP81> CCOOOH = MEO2 + CO2 + OH 1.0/<PAA>
<BP82> RCOOOH + OH = 0.806*RCO3 + 0.194*RO2C + 0.194*yROOH + 0.11*CO2 + 0.11*xOH + 0.11*xCCHO + 0.084*xHO2 + 0.084*xRCHO 6.42e-12
<BP84> HCOCO3 + NO = HO2 + CO + CO2 + NO2 1.0*K<BR31>
<BP85> HCOCO3 + NO2 = HO2 + CO + CO2 + NO3 1.0*K<BR28>
<BP86> HCOCO3 + HO2 = 0.44*OH + 0.44*HO2 + 0.44*CO + 0.44*CO2 + 0.56*GLY + 0.15*O3 1.0*K<BR22>
<PO01> xHCHO = HCHO 1.0?RO2RO
<PO02> xHCHO = XC 1.0?RO2XRO
<PO03> xCCHO = CCHO 1.0?RO2RO
<PO04> xCCHO = 2*XC 1.0?RO2XRO
<PO05> xRCHO = RCHO 1.0?RO2RO
<PO06> xRCHO = 3*XC 1.0?RO2XRO
<PO07> xACETONE = ACETONE 1.0?RO2RO
<PO08> xACETONE = 3*XC 1.0?RO2XRO
<PO09> xMEK = MEK 1.0?RO2RO
<PO10> xMEK = 4*XC 1.0?RO2XRO
<PO11> xPROD2 = PRD2 1.0?RO2RO
<PO12> xPROD2 = 6*XC 1.0?RO2XRO
<PO13> xGLY = GLY 1.0?RO2RO
<PO14> xGLY = 2*XC 1.0?RO2XRO
<PO15> xMGLY = MGLY 1.0?RO2RO
<PO16> xMGLY = 3*XC 1.0?RO2XRO
<PO17> xBACL = BACL 1.0?RO2RO
<PO18> xBACL = 4*XC 1.0?RO2XRO
<PO19> xBALD = BALD 1.0?RO2RO
<PO20> xBALD = 7*XC 1.0?RO2XRO
<PO21> xAFG1 = AFG1 1.0?RO2RO
<PO22> xAFG1 = 5*XC 1.0?RO2XRO
<PO23> xAFG2 = AFG2 1.0?RO2RO
<PO24> xAFG2 = 5*XC 1.0?RO2XRO
<PO25> xAFG3 = AFG3 1.0?RO2RO
<PO26> xAFG3 = 7*XC 1.0?RO2XRO
<PO27> xMACR = MACR 1.0?RO2RO
<PO28> xMACR = 4*XC 1.0?RO2XRO
<PO29> xMVK = MVK 1.0?RO2RO
<PO30> xMVK = 4*XC 1.0?RO2XRO
<PO31> xIPRD = IPRD 1.0?RO2RO
<PO32> xIPRD = 5*XC 1.0?RO2XRO
<PO33> xRNO3 = RNO3 1.0?RO2RO
<PO34> xRNO3 = 6*XC + XN 1.0?RO2XRO
<PO35> zRNO3 = RNO3-1*XN 1.0?RO2NO
<PO36> zRNO3 = PRD2 + HO2 1.0?RO22NN
<PO37> zRNO3 = 6*XC 1.0?RO2XRO
<PO38> yROOH = ROOH-3*XC 1.0?RO2HO2
<PO39> yROOH = MEK-4*XC 1.0?RO2RO2M
<PO40> yROOH = 1.0?RO2RO
<PO41> yR6OOH = R6OOH-6*XC 1.0?RO2HO2
<PO42> yR6OOH = PRD2-6*XC 1.0?RO2RO2M
<PO43> yR6OOH = 1.0?RO2RO
<PO41a> yISOPOOH = ISOPOOH-6*XC 1.0?RO2HO2
<PO42b> yISOPOOH = PRD2-6*XC 1.0?RO2RO2M
<PO43c> yISOPOOH = 1.0?RO2RO
<PO44> yRAOOH = RAOOH-8*XC 1.0?RO2HO2
<PO45> yRAOOH = PRD2-6*XC 1.0?RO2RO2M
<PO46> yRAOOH = 1.0?RO2RO
<PO47> xHOCCHO = HOCCHO 1.0?RO2RO
<PO48> xHOCCHO = 2*XC 1.0?RO2XRO
<PO49> xACROLEIN = ACROLEIN 1.0?RO2RO
<PO50> xACROLEIN = 3*XC 1.0?RO2XRO
<BE01> CH4 + OH = MEO2 1.85e-12*exp(-1690/T)
<BE02> ETHENE + OH = xHO2 + RO2C + 1.61*xHCHO + 0.195*xHOCCHO + yROOH k0=1.00e-28*(T/300)(-4.50), kinf=8.80e-12*(T/300)(-0.85), F=0.60, n=1.0
<BE03> ETHENE + O3 = 0.16*HO2 + 0.16*OH + 0.51*CO + 0.12*CO2 + HCHO + 0.37*HCOOH 9.14e-15*exp(-2580/T)
<BE04> ETHENE + NO3 = xHO2 + RO2C + xRCHO + yROOH + XN-1*XC 3.30e-12*exp(-2880/T)
<BE05> ETHENE + O3P = 0.8*HO2 + 0.29*xHO2 + 0.51*MEO2 + 0.29*RO2C + 0.51*CO + 0.278*xCO + 0.278*xHCHO + 0.1*CCHO + 0.012*xGLY + 0.29*yROOH + 0.2*XC 1.07e-11*exp(-800/T)
<BT01> PROPENE + OH = 0.984*xHO2 + 0.984*RO2C + 0.016*RO2XC + 0.016*zRNO3 + 0.984*xHCHO + 0.984*xCCHO + yROOH-0.048*XC 4.85e-12*exp(504/T)
<BT02> PROPENE + O3 = 0.165*HO2 + 0.35*OH + 0.355*MEO2 + 0.525*CO + 0.215*CO2 + 0.5*HCHO + 0.5*CCHO + 0.185*HCOOH + 0.075*CCOOH + 0.07*XC 5.51e-15*exp(-1878/T)
<BT03> PROPENE + NO3 = 0.949*xHO2 + 0.949*RO2C + 0.051*RO2XC + 0.051*zRNO3 + yROOH + XN + 2.694*XC 4.59e-13*exp(-1156/T)
<BT04> PROPENE + O3P = 0.45*RCHO + 0.55*MEK-0.55*XC 1.02e-11*exp(-280/T)
<BT05> BUTADIENE13 + OH = 0.951*xHO2 + 1.189*RO2C + 0.049*RO2XC + 0.049*zRNO3 + 0.708*xHCHO + 0.48*xACROLEIN + 0.471*xIPRD + yROOH-0.797*XC 1.48e-11*exp(448/T)
<BT06> BUTADIENE13 + O3 = 0.08*HO2 + 0.08*OH + 0.255*CO + 0.185*CO2 + 0.5*HCHO + 0.185*HCOOH + 0.5*ACROLEIN + 0.375*MVK + 0.125*PRD2-0.875*XC 1.34e-14*exp(-2283/T)
<BT07> BUTADIENE13 + NO3 = 0.815*xHO2 + 0.12*xNO2 + 1.055*RO2C + 0.065*RO2XC + 0.065*zRNO3 + 0.115*xHCHO + 0.46*xMVK + 0.12*xIPRD + 0.355*xRNO3 + yROOH + 0.525*XN-1.075*XC 1.00e-13
<BT08> BUTADIENE13 + O3P = 0.25*HO2 + 0.117*xHO2 + 0.118*xMACO3 + 0.235*RO2C + 0.015*RO2XC + 0.015*zRNO3 + 0.115*xCO + 0.115*xACROLEIN + 0.001*xAFG1 + 0.001*xAFG2 + 0.75*PRD2 + 0.25*yROOH-1.532*XC 2.26e-11*exp(-40/T)
<BE06> ISOPRENE + OH = 0.907*xHO2 + 0.986*RO2C + 0.093*RO2XC + 0.093*zRNO3 + 0.624*xHCHO + 0.23*xMACR + 0.32*xMVK + 0.357*xIPRD + yISOPOOH + ISOPRXN-0.167*XC 2.54e-11*exp(410/T)
<BE07> ISOPRENE + O3 = 0.066*HO2 + 0.266*OH + 0.192*xMACO3 + 0.192*RO2C + 0.008*RO2XC + 0.008*zRNO3 + 0.275*CO + 0.122*CO2 + 0.4*HCHO + 0.192*xHCHO + 0.204*HCOOH + 0.39*MACR + 0.16*MVK + 0.15*IPRD + 0.1*PRD2 + 0.2*yR6OOH-0.559*XC 7.86e-15*exp(-1912/T)
<BE08> ISOPRENE + NO3 = 0.749*xHO2 + 0.187*xNO2 + 0.936*RO2C + 0.064*RO2XC + 0.064*zRNO3 + 0.936*xIPRD + yR6OOH + 0.813*XN-0.064*XC 3.03e-12*exp(-448/T)
<BE09> ISOPRENE + O3P = 0.25*MEO2 + 0.24*xMACO3 + 0.24*RO2C + 0.01*RO2XC + 0.01*zRNO3 + 0.24*xHCHO + 0.75*PRD2 + 0.25*yR6OOH-1.01*XC 3.50e-11
<IS88> ISOPOOH + OH = IEPOX + OH 1.9e-11*exp(390/T)
<IS89> ISOPOOH + OH = 0.16*xMVK + .10*xMACR + 0.35*RO2C + 0.05*xRNO3 + 0.26*xHCHO + .04*xRCHO + 0.31*xHO2 + 0.02*ARO2MN + 0.387*yISOPOOH + 0.61*RCHO + 0.61*OH 4.75e-12*exp(200/T)
<IS92> ISOPOOH = OH + 0.91*HO2 + 0.75*HCHO + 0.45*MVK + 0.29*MACR + 0.09*RO2C + 0.11*RCHO + 0.05*ARO2MN-0.16*XC 1.0/<COOH>
<IS90> IEPOX + OH = IEPOXOO 5.78e-11*exp(-400/T)
<IS91> IEPOXOO + HO2 = 0.725*MEK + 0.275*HOCCHO + 0.275*GLY + 0.275*MGLY + 1.125*OH + 0.825*HO2 + 0.200*CO2 + 0.375*HCHO + 0.074*HCOOH + 0.251*CO 2.06e-13*exp(1300/T)
<IS96> IEPOXOO + NO = 0.725*MEK + 0.275*HOCCHO + 0.275*GLY + 0.275*MGLY + 0.125*OH + 0.825*HO2 + 0.200*CO2 + 0.375*HCHO + 0.074*HCOOH + 0.251*CO + NO2 2.60e-12*exp(380/T)
<IS112> IEPOXOO + MEO2 = 0.363*MEK + 0.138*HOCCHO + 0.138*GLY + 0.138*MGLY + 0.063*OH + 0.413*HO2 + 0.100*CO2 + 0.188*HCHO + 0.037*HCOOH + 0.126*CO + 0.5*PRD2 + 0.5*HCHO + 0.5*HO2 + 0.25*HCHO + 0.25*MEOH-0.5*XC 2.00e-13
<IS113> IEPOXOO + RO2C = 0.363*MEK + 0.138*HOCCHO + 0.138*GLY + 0.138*MGLY + 0.063*OH + 0.413*HO2 + 0.100*CO2 + 0.188*HCHO + 0.037*HCOOH + 0.126*CO + 0.5*PRD2-0.5*XC 3.50e-14
<IS114> IEPOXOO + MECO3 = 0.725*MEK + 0.275*HOCCHO + 0.275*GLY + 0.275*MGLY + 0.125*OH + 0.825*HO2 + 0.200*CO2 + 0.375*HCHO + 0.074*HCOOH + 0.251*CO + MEO2 + CO2 4.40e-13*exp(1070/T)
<BT09> APIN + OH = 0.799*xHO2 + 0.004*xRCO3 + 1.042*RO2C + 0.197*RO2XC + 0.197*zRNO3 + 0.002*xCO + 0.022*xHCHO + 0.776*xRCHO + 0.034*xACETONE + 0.02*xMGLY + 0.023*xBACL + yR6OOH + TRPRXN + 6.2*XC 1.21e-11*exp(436/T)
<BT10> APIN + O3 = 0.009*HO2 + 0.102*xHO2 + 0.728*OH + 0.001*xMECO3 + 0.297*xRCO3 + 1.511*RO2C + 0.337*RO2XC + 0.337*zRNO3 + 0.029*CO + 0.051*xCO + 0.017*CO2 + 0.344*xHCHO + 0.24*xRCHO + 0.345*xACETONE + 0.008*MEK + 0.002*xGLY + 0.081*xBACL + 0.255*PRD2 + 0.737*yR6OOH + TRPRXN + 2.999*XC 5.00e-16*exp(-530/T)
<BT11> APIN + NO3 = 0.056*xHO2 + 0.643*xNO2 + 0.007*xRCO3 + 1.05*RO2C + 0.293*RO2XC + 0.293*zRNO3 + 0.005*xCO + 0.007*xHCHO + 0.684*xRCHO + 0.069*xACETONE + 0.002*xMGLY + 0.056*xRNO3 + yR6OOH + 0.301*XN + TRPRXN + 5.608*XC 1.19e-12*exp(490/T)
<BT12> APIN + O3P = PRD2 + TRPRXN + 4*XC 3.20e-11
<BE13> ACETYLENE + OH = 0.3*HO2 + 0.7*OH + 0.3*CO + 0.3*HCOOH + 0.7*GLY k0=5.50e-30, kinf=8.30e-13*(T/300)(-2.00), F=0.60, n=1.0
<BE14> ACETYLENE + O3 = 1.5*HO2 + 0.5*OH + 1.5*CO + 0.5*CO2 1.00e-14*exp(-4100/T)
<BE15> BENZENE + OH = 0.57*HO2 + 0.29*xHO2 + 0.116*OH + 0.29*RO2C + 0.024*RO2XC + 0.024*zRNO3 + 0.29*xGLY + 0.57*CRES + 0.029*xAFG1 + 0.261*xAFG2 + 0.116*AFG3 + 0.314*yRAOOH + BENZRO2-0.976*XC 2.33e-12*exp(-193/T)
<BT13> TOLUENE + OH = 0.181*HO2 + 0.454*xHO2 + 0.312*OH + 0.454*RO2C + 0.054*RO2XC + 0.054*zRNO3 + 0.238*xGLY + 0.151*xMGLY + 0.181*CRES + 0.065*xBALD + 0.195*xAFG1 + 0.195*xAFG2 + 0.312*AFG3 + 0.073*yR6OOH + 0.435*yRAOOH + TOLRO2-0.109*XC 1.81e-12*exp(338/T)
<BT14> MXYL + OH = 0.159*HO2 + 0.52*xHO2 + 0.239*OH + 0.52*RO2C + 0.082*RO2XC + 0.082*zRNO3 + 0.1*xGLY + 0.38*xMGLY + 0.159*CRES + 0.041*xBALD + 0.336*xAFG1 + 0.144*xAFG2 + 0.239*AFG3 + 0.047*yR6OOH + 0.555*yRAOOH + XYLRO2 + 0.695*XC 2.31e-11
<BT15> OXYL + OH = 0.161*HO2 + 0.554*xHO2 + 0.198*OH + 0.554*RO2C + 0.087*RO2XC + 0.087*zRNO3 + 0.084*xGLY + 0.238*xMGLY + 0.185*xBACL + 0.161*CRES + 0.047*xBALD + 0.253*xAFG1 + 0.253*xAFG2 + 0.198*AFG3 + 0.055*yR6OOH + 0.586*yRAOOH + XYLRO2 + 0.484*XC 1.36e-11
<BT16> PXYL + OH = 0.159*HO2 + 0.487*xHO2 + 0.278*OH + 0.487*RO2C + 0.076*RO2XC + 0.076*zRNO3 + 0.286*xGLY + 0.112*xMGLY + 0.159*CRES + 0.088*xBALD + 0.045*xAFG1 + 0.067*xAFG2 + 0.278*AFG3 + 0.286*xAFG3 + 0.102*yR6OOH + 0.461*yRAOOH + XYLRO2 + 0.399*XC 1.43e-11
<BT17> TMBENZ124 + OH = 0.022*HO2 + 0.627*xHO2 + 0.23*OH + 0.627*RO2C + 0.121*RO2XC + 0.121*zRNO3 + 0.074*xGLY + 0.405*xMGLY + 0.112*xBACL + 0.022*CRES + 0.036*xBALD + 0.088*xAFG1 + 0.352*xAFG2 + 0.23*AFG3 + 0.151*xAFG3 + 0.043*yR6OOH + 0.705*yRAOOH + XYLRO2 + 1.19*XC 3.25e-11
<BT18> ETOH + OH = 0.95*HO2 + 0.05*xHO2 + 0.05*RO2C + 0.081*xHCHO + 0.95*CCHO + 0.01*xHOCCHO + 0.05*yROOH-0.001*XC 5.49e-13*(T/300)(2.00)*exp(530/T)
<BL01> ALK1 + OH = xHO2 + RO2C + xCCHO + yROOH 1.34e-12*(T/300)(2.00)*exp(-499/T)
<BL02> ALK2 + OH = 0.965*xHO2 + 0.965*RO2C + 0.035*RO2XC + 0.035*zRNO3 + 0.261*xRCHO + 0.704*xACETONE + yROOH-0.105*XC 1.49e-12*(T/300)(2.00)*exp(-87/T)
<BL03> ALK3 + OH = 0.695*xHO2 + 0.236*xTBUO + 1.253*RO2C + 0.07*RO2XC + 0.07*zRNO3 + 0.026*xHCHO + 0.445*xCCHO + 0.122*xRCHO + 0.024*xACETONE + 0.332*xMEK + 0.983*yROOH + 0.017*yR6OOH-0.046*XC 1.51e-12*exp(126/T)
<BL04> ALK4 + OH = 0.83*xHO2 + 0.01*xMEO2 + 0.011*xMECO3 + 1.763*RO2C + 0.149*RO2XC + 0.149*zRNO3 + 0.002*xCO + 0.029*xHCHO + 0.438*xCCHO + 0.236*xRCHO + 0.426*xACETONE + 0.106*xMEK + 0.146*xPROD2 + yR6OOH-0.119*XC 3.75e-12*exp(44/T)
<BL05> ALK5 + OH = 0.647*xHO2 + 1.605*RO2C + 0.353*RO2XC + 0.353*zRNO3 + 0.04*xHCHO + 0.106*xCCHO + 0.209*xRCHO + 0.071*xACETONE + 0.086*xMEK + 0.407*xPROD2 + yR6OOH + 2.004*XC 2.70e-12*exp(374/T)
<AALK> SOAALK + OH = OH + 0.47*ALKRXN 2.70e-12*exp(374/T)
<BL06> OLE1 + OH = 0.871*xHO2 + 0.001*xMEO2 + 1.202*RO2C + 0.128*RO2XC + 0.128*zRNO3 + 0.582*xHCHO + 0.01*xCCHO + 0.007*xHOCCHO + 0.666*xRCHO + 0.007*xACETONE + 0.036*xACROLEIN + 0.001*xMACR + 0.012*xMVK + 0.009*xIPRD + 0.168*xPROD2 + 0.169*yROOH + 0.831*yR6OOH + 0.383*XC 6.72e-12*exp(501/T)
<BL07> OLE1 + O3 = 0.095*HO2 + 0.057*xHO2 + 0.128*OH + 0.09*RO2C + 0.005*RO2XC + 0.005*zRNO3 + 0.303*CO + 0.088*CO2 + 0.5*HCHO + 0.011*xCCHO + 0.5*RCHO + 0.044*xRCHO + 0.003*xACETONE + 0.009*MEK + 0.185*HCOOH + 0.159*RCOOH + 0.268*PRD2 + 0.011*yROOH + 0.052*yR6OOH + 0.11*XC 3.19e-15*exp(-1701/T)
<BL08> OLE1 + NO3 = 0.772*xHO2 + 1.463*RO2C + 0.228*RO2XC + 0.228*zRNO3 + 0.013*xCCHO + 0.003*xRCHO + 0.034*xACETONE + 0.774*xRNO3 + 0.169*yROOH + 0.831*yR6OOH + 0.226*XN-1.149*XC 5.37e-13*exp(-1047/T)
<BL09> OLE1 + O3P = 0.45*RCHO + 0.39*MEK + 0.16*PRD2 + 1.13*XC 1.61e-11*exp(-326/T)
<BL10> OLE2 + OH = 0.912*xHO2 + 0.953*RO2C + 0.088*RO2XC + 0.088*zRNO3 + 0.179*xHCHO + 0.835*xCCHO + 0.51*xRCHO + 0.144*xACETONE + 0.08*xMEK + 0.002*xMVK + 0.012*xIPRD + 0.023*xPROD2 + 0.319*yROOH + 0.681*yR6OOH + 0.135*XC 1.26e-11*exp(488/T)
<BL11> OLE2 + O3 = 0.094*HO2 + 0.041*xHO2 + 0.443*OH + 0.307*MEO2 + 0.156*xMECO3 + 0.008*xRCO3 + 0.212*RO2C + 0.003*RO2XC + 0.003*zRNO3 + 0.299*CO + 0.161*CO2 + 0.131*HCHO + 0.114*xHCHO + 0.453*CCHO + 0.071*xCCHO + 0.333*RCHO + 0.019*xRCHO + 0.051*ACETONE + 0.033*MEK + 0.001*xMEK + 0.024*HCOOH + 0.065*CCOOH + 0.235*RCOOH + 0.037*PRD2 + 0.073*yROOH + 0.136*yR6OOH + 0.16*XC 8.59e-15*exp(-1255/T)
<BL12> OLE2 + NO3 = 0.4*xHO2 + 0.426*xNO2 + 0.035*xMEO2 + 1.193*RO2C + 0.14*RO2XC + 0.14*zRNO3 + 0.072*xHCHO + 0.579*xCCHO + 0.163*xRCHO + 0.116*xACETONE + 0.002*xMEK + 0.32*xRNO3 + 0.319*yROOH + 0.681*yR6OOH + 0.254*XN + 0.13*XC 2.31e-13*exp(382/T)
<BL13> OLE2 + O3P = 0.079*RCHO + 0.751*MEK + 0.17*PRD2 + 0.739*XC 1.43e-11*exp(111/T)
<BL14> ARO1 + OH = 0.123*HO2 + 0.566*xHO2 + 0.202*OH + 0.566*RO2C + 0.11*RO2XC + 0.11*zRNO3 + 0.158*xGLY + 0.1*xMGLY + 0.123*CRES + 0.072*xAFG1 + 0.185*xAFG2 + 0.202*AFG3 + 0.309*xPROD2 + 0.369*yR6OOH + TOLRO2 + 0.31*XC 7.84e-12
<BL15> ARO2MN + OH = 0.077*HO2 + 0.617*xHO2 + 0.178*OH + 0.617*RO2C + 0.128*RO2XC + 0.128*zRNO3 + 0.088*xGLY + 0.312*xMGLY + 0.134*xBACL + 0.077*CRES + 0.026*xBALD + 0.221*xAFG1 + 0.247*xAFG2 + 0.178*AFG3 + 0.068*xAFG3 + 0.057*xPROD2 + 0.101*yR6OOH + XYLRO2 + 1.459*XC 3.09e-11
<BL15b> NAPHTHAL + OH = 0.077*HO2 + 0.617*xHO2 + 0.178*OH + 0.617*RO2C + 0.128*RO2XC + 0.128*zRNO3 + 0.088*xGLY + 0.312*xMGLY + 0.134*xBACL + 0.077*CRES + 0.026*xBALD + 0.221*xAFG1 + 0.247*xAFG2 + 0.178*AFG3 + 0.068*xAFG3 + 0.057*xPROD2 + 0.101*yR6OOH + PAHRO2 + 1.459*XC 3.09e-11
<BL16> TERP + OH = 0.734*xHO2 + 0.064*xRCO3 + 1.211*RO2C + 0.201*RO2XC + 0.201*zRNO3 + 0.001*xCO + 0.411*xHCHO + 0.385*xRCHO + 0.037*xACETONE + 0.007*xMEK + 0.003*xMGLY + 0.009*xBACL + 0.003*xMVK + 0.002*xIPRD + 0.409*xPROD2 + yR6OOH + TRPRXN + 4.375*XC 2.27e-11*exp(435/T)
<BL17> TERP + O3 = 0.078*HO2 + 0.046*xHO2 + 0.499*OH + 0.202*xMECO3 + 0.059*xRCO3 + 0.49*RO2C + 0.121*RO2XC + 0.121*zRNO3 + 0.249*CO + 0.063*CO2 + 0.127*HCHO + 0.033*xHCHO + 0.208*xRCHO + 0.057*xACETONE + 0.002*MEK + 0.172*HCOOH + 0.068*RCOOH + 0.003*xMGLY + 0.039*xBACL + 0.002*xMACR + 0.001*xIPRD + 0.502*PRD2 + 0.428*yR6OOH + TRPRXN + 3.852*XC 8.28e-16*exp(-785/T)
<BL18> TERP + NO3 = 0.227*xHO2 + 0.287*xNO2 + 0.026*xRCO3 + 1.786*RO2C + 0.46*RO2XC + 0.46*zRNO3 + 0.012*xCO + 0.023*xHCHO + 0.002*xHOCCHO + 0.403*xRCHO + 0.239*xACETONE + 0.005*xMACR + 0.001*xMVK + 0.004*xIPRD + 0.228*xRNO3 + yR6OOH + 0.485*XN + TRPRXN + 3.785*XC 1.33e-12*exp(490/T)
<BL19> TERP + O3P = 0.237*RCHO + 0.763*PRD2 + TRPRXN + 4.711*XC 4.02e-11
<BT19> SESQ + OH = 0.734*xHO2 + 0.064*xRCO3 + 1.211*RO2C + 0.201*RO2XC + 0.201*zRNO3 + 0.001*xCO + 0.411*xHCHO + 0.385*xRCHO + 0.037*xACETONE + 0.007*xMEK + 0.003*xMGLY + 0.009*xBACL + 0.003*xMVK + 0.002*xIPRD + 0.409*xPROD2 + yR6OOH + SESQRXN + 9.375*XC 1.0*K<BL16>
<BT20> SESQ + O3 = 0.078*HO2 + 0.046*xHO2 + 0.499*OH + 0.202*xMECO3 + 0.059*xRCO3 + 0.49*RO2C + 0.121*RO2XC + 0.121*zRNO3 + 0.249*CO + 0.063*CO2 + 0.127*HCHO + 0.033*xHCHO + 0.208*xRCHO + 0.057*xACETONE + 0.002*MEK + 0.172*HCOOH + 0.068*RCOOH + 0.003*xMGLY + 0.039*xBACL + 0.002*xMACR + 0.001*xIPRD + 0.502*PRD2 + 0.428*yR6OOH + SESQRXN + 8.852*XC 1.0*K<BL17>
<BT21> SESQ + NO3 = 0.227*xHO2 + 0.287*xNO2 + 0.026*xRCO3 + 1.786*RO2C + 0.46*RO2XC + 0.46*zRNO3 + 0.012*xCO + 0.023*xHCHO + 0.002*xCCHO + 0.403*xRCHO + 0.239*xACETONE + 0.005*xMACR + 0.001*xMVK + 0.004*xIPRD + 0.228*xRNO3 + yR6OOH + 0.485*XN + SESQRXN + 8.785*XC 1.0*K<BL18>
<BT22> SESQ + O3P = 0.237*RCHO + 0.763*PRD2 + SESQRXN + 9.711*XC 1.0*K<BL19>
<CI01> CL2 = 2*CL 1.0/<CL2>
<CI02> CL + NO + M = CLNO 7.60e-32*(T/300)(-1.80)
<CI03> CLNO = CL + NO 1.0/<CLNO_06>
<CI04> CL + NO2 = CLONO k0=1.30e-30*(T/300)(-2.00), kinf=1.00e-10*(T/300)(-1.00), F=0.60, n=1.0
<CI05> CL + NO2 = CLNO2 k0=1.80e-31*(T/300)(-2.00), kinf=1.00e-10*(T/300)(-1.00), F=0.60, n=1.0
<CI06> CLONO = CL + NO2 1.0/<CLONO>
<CI07> CLNO2 = CL + NO2 1.0/<CLNO2>
<CI08> CL + HO2 = HCL 3.44e-11*(T/300)(-0.56)
<CI09> CL + HO2 = CLO + OH 9.41e-12*(T/300)(2.10)
<CI10> CL + O3 = CLO 2.80e-11*exp(-250/T)
<CI11> CL + NO3 = CLO + NO2 2.40e-11
<CI12> CLO + NO = CL + NO2 6.20e-12*exp(295/T)
<CI13> CLO + NO2 = CLONO2 k0=1.80e-31*(T/300)(-3.40), kinf=1.50e-11*(T/300)(-1.90), F=0.60, n=1.0
<CI14> CLONO2 = CLO + NO2 1.0/<CLONO2_1>
<CI15> CLONO2 = CL + NO3 1.0/<CLONO2_2>
<CI16> CLONO2 = CLO + NO2 k0=4.48e-05*(T/300)(-1.00)*exp(-12530/T), kinf=3.71e15*(T/300)(3.50)*exp(-12530/T), F=0.60, n=1.0
<CI17> CL + CLONO2 = CL2 + NO3 6.20e-12*exp(145/T)
<CI18> CLO + HO2 = HOCL 2.20e-12*exp(340/T)
<CI19> HOCL = OH + CL 1.0/<HOCL_06>
<CI20> CLO + CLO = 0.29*CL2 + 1.42*CL 1.25e-11*exp(-1960/T)
<CI21> OH + HCL = CL 1.70e-12*exp(-230/T)
<CI22> CL + H2 = HCL + HO2 3.90e-11*exp(-2310/T)
<CP01> HCHO + CL = HCL + HO2 + CO 8.10e-11*exp(-30/T)
<CP02> CCHO + CL = HCL + MECO3 8.00e-11
<CP03> MEOH + CL = HCL + HCHO + HO2 5.50e-11
<CP04> RCHO + CL = HCL + 0.9*RCO3 + 0.1*RO2C + 0.1*xCCHO + 0.1*xCO + 0.1*xHO2 + 0.1*yROOH 1.23e-10
<CP05> ACETONE + CL = HCL + RO2C + xHCHO + xMECO3 + yROOH 7.70e-11*exp(-1000/T)
<CP06> MEK + CL = HCL + 0.975*RO2C + 0.039*RO2XC + 0.039*zRNO3 + 0.84*xHO2 + 0.085*xMECO3 + 0.036*xRCO3 + 0.065*xHCHO + 0.07*xCCHO + 0.84*xRCHO + yROOH + 0.763*XC 3.60e-11
<CP07> RNO3 + CL = HCL + 0.038*NO2 + 0.055*HO2 + 1.282*RO2C + 0.202*RO2XC + 0.202*zRNO3 + 0.009*RCHO + 0.018*MEK + 0.012*PRD2 + 0.055*RNO3 + 0.159*xNO2 + 0.547*xHO2 + 0.045*xHCHO + 0.3*xCCHO + 0.02*xRCHO + 0.003*xACETONE + 0.041*xMEK + 0.046*xPROD2 + 0.547*xRNO3 + 0.908*yR6OOH + 0.201*XN-0.149*XC 1.92e-10
<CP08> PRD2 + CL = HCL + 0.314*HO2 + 0.68*RO2C + 0.116*RO2XC + 0.116*zRNO3 + 0.198*RCHO + 0.116*PRD2 + 0.541*xHO2 + 0.007*xMECO3 + 0.022*xRCO3 + 0.237*xHCHO + 0.109*xCCHO + 0.591*xRCHO + 0.051*xMEK + 0.04*xPROD2 + 0.686*yR6OOH + 1.262*XC 2.00e-10
<CP09> GLY + CL = HCL + 0.63*HO2 + 1.26*CO + 0.37*RCO3-0.37*XC 8.10e-11*exp(-30/T)
<CP10> MGLY + CL = HCL + CO + MECO3 8.00e-11
<CP11> CRES + CL = HCL + xHO2 + xBALD + yR6OOH 6.20e-11
<CP12> BALD + CL = HCL + BZCO3 8.00e-11
<CP13> ROOH + CL = HCL + 0.414*OH + 0.588*RO2C + 0.414*RCHO + 0.104*xOH + 0.482*xHO2 + 0.106*xHCHO + 0.104*xCCHO + 0.197*xRCHO + 0.285*xMEK + 0.586*yROOH-0.287*XC 1.66e-10
<CP14> R6OOH + CL = HCL + 0.145*OH + 1.078*RO2C + 0.117*RO2XC + 0.117*zRNO3 + 0.145*PRD2 + 0.502*xOH + 0.237*xHO2 + 0.186*xCCHO + 0.676*xRCHO + 0.28*xPROD2 + 0.855*yR6OOH + 0.348*XC 3.00e-10
<CP15> RAOOH + CL = 0.404*HCL + 0.139*OH + 0.148*HO2 + 0.589*RO2C + 0.124*RO2XC + 0.124*zRNO3 + 0.074*PRD2 + 0.147*MGLY + 0.139*IPRD + 0.565*xHO2 + 0.024*xOH + 0.448*xRCHO + 0.026*xGLY + 0.03*xMEK + 0.252*xMGLY + 0.073*xAFG1 + 0.073*xAFG2 + 0.713*yR6OOH + 2.674*XC 4.29e-10
<TP01> ACROLEIN + CL = 0.484*xHO2 + 0.274*xCL + 0.216*MACO3 + 1.032*RO2C + 0.026*RO2XC + 0.026*zRNO3 + 0.216*HCL + 0.484*xCO + 0.274*xHCHO + 0.274*xGLY + 0.484*xCLCCHO + 0.784*yROOH-0.294*XC 2.94e-10
<CP16> MACR + CL = 0.25*HCL + 0.165*MACO3 + 0.802*RO2C + 0.033*RO2XC + 0.033*zRNO3 + 0.802*xHO2 + 0.541*xCO + 0.082*xIPRD + 0.18*xCLCCHO + 0.541*xCLACET + 0.835*yROOH + 0.208*XC 3.85e-10
<CP17> MVK + CL = 1.283*RO2C + 0.053*RO2XC + 0.053*zRNO3 + 0.322*xHO2 + 0.625*xMECO3 + 0.947*xCLCCHO + yROOH + 0.538*XC 2.32e-10
<CP18> IPRD + CL = 0.401*HCL + 0.084*HO2 + 0.154*MACO3 + 0.73*RO2C + 0.051*RO2XC + 0.051*zRNO3 + 0.042*AFG1 + 0.042*AFG2 + 0.712*xHO2 + 0.498*xCO + 0.195*xHCHO + 0.017*xMGLY + 0.009*xAFG1 + 0.009*xAFG2 + 0.115*xIPRD + 0.14*xCLCCHO + 0.42*xCLACET + 0.762*yR6OOH + 0.709*XC 4.12e-10
<CP19> CLCCHO = HO2 + CO + RO2C + xCL + xHCHO + yROOH 1.0/<CLCCHO>
<CP20> CLCCHO + OH = RCO3-1*XC 3.10e-12
<CP21> CLCCHO + CL = HCL + RCO3-1*XC 1.29e-11
<CP22> CLACET = MECO3 + RO2C + xCL + xHCHO + yROOH 5.00e-1/<CLACET>
<CP23> xCL = CL 1.0?RO2RO
<CP24> xCL = 1.0?RO2XRO
<CP25> xCLCCHO = CLCCHO 1.0?RO2RO
<CP26> xCLCCHO = 2*XC 1.0?RO2XRO
<CP27> xCLACET = CLACET 1.0?RO2RO
<CP28> xCLACET = 3*XC 1.0?RO2XRO
<CE01> CH4 + CL = HCL + MEO2 7.30e-12*exp(-1280/T)
<CE02> ETHENE + CL = xHO2 + 2*RO2C + xHCHO + CLCHO k0=1.60e-29*(T/300)(-3.30), kinf=3.10e-10*(T/300)(-1.00), F=0.60, n=1.0
<TE01> PROPENE + CL = 0.124*HCL + 0.971*xHO2 + 0.971*RO2C + 0.029*RO2XC + 0.029*zRNO3 + 0.124*xACROLEIN + 0.306*xCLCCHO + 0.54*xCLACET + yROOH + 0.222*XC 2.67e-10
<TE02> BUTADIENE13 + CL = 0.39*xHO2 + 0.541*xCL + 1.884*RO2C + 0.069*RO2XC + 0.069*zRNO3 + 0.863*xHCHO + 0.457*xACROLEIN + 0.473*xIPRD + yROOH-1.013*XC 4.90e-10
<CE03> ISOPRENE + CL = 0.15*HCL + 0.738*xHO2 + 0.177*xCL + 1.168*RO2C + 0.085*RO2XC + 0.085*zRNO3 + 0.275*xHCHO + 0.177*xMVK + 0.671*xIPRD + 0.067*xCLCCHO + yR6OOH + 0.018*XC 4.80e-10
<TE03> APIN + CL = 0.548*HCL + 0.252*xHO2 + 0.068*xCL + 0.034*xMECO3 + 0.05*xRCO3 + 0.016*xMACO3 + 2.258*RO2C + 0.582*RO2XC + 0.582*zRNO3 + 0.035*xCO + 0.158*xHCHO + 0.185*xRCHO + 0.274*xACETONE + 0.007*xGLY + 0.003*xBACL + 0.003*xMVK + 0.158*xIPRD + 0.006*xAFG1 + 0.006*xAFG2 + 0.001*xAFG3 + 0.109*xCLCCHO + yR6OOH + 3.543*XC 5.46e-10
<CE04> ACETYLENE + CL = HO2 + CO + XC k0=5.20e-30*(T/300)(-2.40), kinf=2.20e-10, F=0.60, n=1.0
<TE04> TOLUENE + CL = 0.894*xHO2 + 0.894*RO2C + 0.106*RO2XC + 0.106*zRNO3 + 0.894*xBALD + 0.106*XC 6.20e-11
<TE05> MXYL + CL = 0.864*xHO2 + 0.864*RO2C + 0.136*RO2XC + 0.136*zRNO3 + 0.864*xBALD + 1.136*XC 1.35e-10
<TE06> OXYL + CL = 0.864*xHO2 + 0.864*RO2C + 0.136*RO2XC + 0.136*zRNO3 + 0.864*xBALD + 1.136*XC 1.40e-10
<TE07> PXYL + CL = 0.864*xHO2 + 0.864*RO2C + 0.136*RO2XC + 0.136*zRNO3 + 0.864*xBALD + 1.136*XC 1.44e-10
<TE08> TMBENZ124 + CL = 0.838*xHO2 + 0.838*RO2C + 0.162*RO2XC + 0.162*zRNO3 + 0.838*xBALD + 2.162*XC 2.42e-10
<TE09> ETOH + CL = HCL + 0.688*HO2 + 0.312*xHO2 + 0.312*RO2C + 0.503*xHCHO + 0.688*CCHO + 0.061*xHOCCHO + 0.312*yROOH-0.001*XC 8.60e-11*exp(45/T)
<BC01> ALK1 + CL = HCL + xHO2 + RO2C + xCCHO + yROOH 8.30e-11*exp(-100/T)
<BC02> ALK2 + CL = HCL + 0.97*xHO2 + 0.97*RO2C + 0.03*RO2XC + 0.03*zRNO3 + 0.482*xRCHO + 0.488*xACETONE + yROOH-0.09*XC 1.20e-10*exp(40/T)
<BC03> ALK3 + CL = HCL + 0.835*xHO2 + 0.094*xTBUO + 1.361*RO2C + 0.07*RO2XC + 0.07*zRNO3 + 0.078*xHCHO + 0.34*xCCHO + 0.343*xRCHO + 0.075*xACETONE + 0.253*xMEK + 0.983*yROOH + 0.017*yR6OOH + 0.18*XC 1.86e-10
<BC04> ALK4 + CL = HCL + 0.827*xHO2 + 0.003*xMEO2 + 0.004*xMECO3 + 1.737*RO2C + 0.165*RO2XC + 0.165*zRNO3 + 0.003*xCO + 0.034*xHCHO + 0.287*xCCHO + 0.412*xRCHO + 0.247*xACETONE + 0.076*xMEK + 0.13*xPROD2 + yR6OOH + 0.327*XC 2.63e-10
<BC05> ALK5 + CL = HCL + 0.647*xHO2 + 1.541*RO2C + 0.352*RO2XC + 0.352*zRNO3 + 0.022*xHCHO + 0.08*xCCHO + 0.258*xRCHO + 0.044*xACETONE + 0.041*xMEK + 0.378*xPROD2 + yR6OOH + 2.368*XC 4.21e-10
<BC06> OLE1 + CL = 0.384*HCL + 0.873*xHO2 + 1.608*RO2C + 0.127*RO2XC + 0.127*zRNO3 + 0.036*xHCHO + 0.206*xCCHO + 0.072*xRCHO + 0.215*xACROLEIN + 0.019*xMVK + 0.038*xIPRD + 0.192*xCLCCHO + 0.337*xCLACET + 0.169*yROOH + 0.831*yR6OOH + 1.268*XC 3.92e-10
<BC07> OLE2 + CL = 0.279*HCL + 0.45*xHO2 + 0.442*xCL + 0.001*xMEO2 + 1.492*RO2C + 0.106*RO2XC + 0.106*zRNO3 + 0.19*xHCHO + 0.383*xCCHO + 0.317*xRCHO + 0.086*xACETONE + 0.042*xMEK + 0.025*xMACR + 0.058*xMVK + 0.161*xIPRD + 0.013*xCLCCHO + 0.191*xCLACET + 0.319*yROOH + 0.681*yR6OOH + 0.294*XC 3.77e-10
<BC08> ARO1 + CL = 0.84*xHO2 + 0.84*RO2C + 0.16*RO2XC + 0.16*zRNO3 + 0.84*xPROD2 + XC 2.16e-10
<BC09> ARO2MN + CL = 0.828*xHO2 + 0.828*RO2C + 0.172*RO2XC + 0.172*zRNO3 + 0.469*xBALD + 0.359*xPROD2 + 2.531*XC 2.66e-10
<BC09b> NAPHTHAL + CL = 0.828*xHO2 + 0.828*RO2C + 0.172*RO2XC + 0.172*zRNO3 + 0.469*xBALD + 0.359*xPROD2 + 2.531*XC 2.66e-10
<BC10> TERP + CL = 0.548*HCL + 0.252*xHO2 + 0.068*xCL + 0.034*xMECO3 + 0.05*xRCO3 + 0.016*xMACO3 + 2.258*RO2C + 0.582*RO2XC + 0.582*zRNO3 + 0.035*xCO + 0.158*xHCHO + 0.185*xRCHO + 0.274*xACETONE + 0.007*xGLY + 0.003*xBACL + 0.003*xMVK + 0.158*xIPRD + 0.006*xAFG1 + 0.006*xAFG2 + 0.001*xAFG3 + 0.109*xCLCCHO + yR6OOH + 3.543*XC 5.46e-10
<BC11> SESQ + CL = 0.252*xHO2 + 0.068*xCL + 0.034*xMECO3 + 0.05*xRCO3 + 0.016*xMACO3 + 2.258*RO2C + 0.582*RO2XC + 0.582*zRNO3 + 0.548*HCL + 0.035*xCO + 0.158*xHCHO + 0.185*xRCHO + 0.274*xACETONE + 0.007*xGLY + 0.003*xBACL + 0.003*xMVK + 0.158*xIPRD + 0.006*xAFG1 + 0.006*xAFG2 + 0.001*xAFG3 + 0.109*xCLCCHO + yR6OOH + 8.543*XC 1.0*K<BC10>
<AE51> BENZRO2 + NO = NO + BNZNRXN 1.0*K<BR07>
<AE52> BENZRO2 + HO2 = HO2 + BNZHRXN 1.0*K<BR08>
<AE53> XYLRO2 + NO = NO + XYLNRXN 1.0*K<BR07>
<AE54> XYLRO2 + HO2 = HO2 + XYLHRXN 1.0*K<BR08>
<AE55> TOLRO2 + NO = NO + TOLNRXN 1.0*K<BR07>
<AE56> TOLRO2 + HO2 = HO2 + TOLHRXN 1.0*K<BR08>
<AE55b> PAHRO2 + NO = NO + PAHNRXN 1.0*K<BR07>
<AE56b> PAHRO2 + HO2 = HO2 + PAHHRXN 1.0*K<BR08>
<TR01> HCHO_PRIMARY = 1.0/<HCHOR_06>
<TR02> HCHO_PRIMARY = 1.0/<HCHOM_06>
<TR03> HCHO_PRIMARY + OH = OH 5.40e-12*exp(135/T)
<TR05> HCHO_PRIMARY + NO3 = NO3 2.00e-12*exp(-2431/T)
<TR06> HCHO_PRIMARY + CL = CL 8.10e-11*exp(-30/T)
<TR07> CCHO_PRIMARY + OH = OH 4.40e-12*exp(365/T)
<TR08> CCHO_PRIMARY = 1.0/<CCHO_R>
<TR09> CCHO_PRIMARY + NO3 = NO3 1.40e-12*exp(-1860/T)
<TR10> CCHO_PRIMARY + CL = CL 8.00e-11
<TR11> ACRO_PRIMARY + OH = OH 1.99e-11
<TR12> ACRO_PRIMARY + O3 = O3 1.40e-15*exp(-2528/T)
<TR13> ACRO_PRIMARY + NO3 = NO3 1.18e-15
<TR14> ACRO_PRIMARY + O3P = O3P 2.37e-12
<TR15> ACRO_PRIMARY = 1.0/<ACRO_09>
<TR16> ACRO_PRIMARY + CL = CL 2.94e-10
<HET_N02> NO2 = 0.5*HONO + 0.5*HNO3 1.0~<HETERO_NO2>
<HET_N2O5IJ> N2O5 = HNO3 + H2NO3PIJ 1.0~<HETERO_N2O5IJ>
<HET_N2O5K> N2O5 = HNO3 + H2NO3PK 1.0~<HETERO_N2O5K>
<HET_H2NO3PIJA> H2NO3PIJ = HNO3 1.0~<HETERO_H2NO3PAIJ>
<HET_H2NO3PKA> H2NO3PK = HNO3 1.0~<HETERO_H2NO3PAK>
<HET_H2NO3PIB> H2NO3PIJ + ACLI = CLNO2 1.0~<HETERO_H2NO3PBIJ>
<HET_H2NO3PJB> H2NO3PIJ + ACLJ = CLNO2 1.0~<HETERO_H2NO3PBIJ>
<HET_H2NO3PKB> H2NO3PK + ACLK = CLNO2 1.0~<HETERO_H2NO3PBK>
<HAL_Ozone> O3 = min(1.0E-40*exp(78.4256*P)+4.0582E-9*exp(5.8212*P), 2.4E-06) Set to zero if sun is below the horizon and if surface does not include sea or surf zones; P equals air pressure in atmospheres CMAQv5.1_Halogen_chemistry
<OLIG_XYLENE1> AXYL1J = 1.1428*AOLGAJ 9.48816E-6
<OLIG_XYLENE2> AXYL2J = 1.1428*AOLGAJ 9.48816E-6
<OLIG_TOLUENE1> ATOL1J = 1.0000*AOLGAJ 9.48816E-6
<OLIG_TOLUENE2> ATOL2J = 1.0000*AOLGAJ 9.48816E-6
<OLIG_BENZENE1> ABNZ1J = 0.85714*AOLGAJ 9.48816E-6
<OLIG_BENZENE2> ABNZ2J = 0.85714*AOLGAJ 9.48816E-6
<OLIG_TERPENE1> ATRP1J = 1.0000*AOLGBJ 9.48816E-6
<OLIG_TERPENE2> ATRP2J = 1.0000*AOLGBJ 9.48816E-6
<OLIG_ISOPRENE1> AISO1J = 0.50*AOLGBJ 9.48816E-6
<OLIG_ISOPRENE2> AISO2J = 0.50*AOLGBJ 9.48816E-6
<OLIG_SESQT1> ASQTJ = 1.50*AOLGBJ 9.48816E-6
<OLIG_PAH1> APAH1J = 1.4286*AOLGAJ 9.48816E-6
<OLIG_PAH2> APAH2J = 1.4286*AOLGAJ 9.48816E-6
<OLIG_ALK1> AALK1J = 1.7143*AOLGAJ 9.48816E-6
<OLIG_ALK2> AALK2J = 1.7143*AOLGAJ 9.48816E-6
<RPOAGEPI> APOCI + OH = 1.25*APNCOMI + APOCI + OH 2.5E-12
<RPOAGELI> APNCOMI + OH = OH 1.0~<HETERO_PNCOMLI>
<RPOAGEPJ> APOCJ + OH = 1.25*APNCOMJ + APOCJ + OH 2.5E-12
<RPOAGELJ> APNCOMJ + OH = OH 1.0~<HETERO_PNCOMLJ>
<HET_IEPOX> IEPOX = AISO3J 1.0~<HETERO_IEPOX>
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