Cb05tump ae6 v5.1 mech.def
cb05tump contains all the gas-phase reactions of cb05tucl_ae6_aq plus these additional reactions:
- For rate constants with the form A/<PHOT>, k equals A times the photolysis rates, PHOT.
- Units of rate constants give reactions rates in units of molecules cm-3 s-1. Note that T equals air temperature in degrees K in the below table.
Check the species table for the reactants and products added to the cb05tucl reactant and products.
| Label | Reaction | Rate Const | Notes | Reference |
|---|---|---|---|---|
| <T01> | FORM_PRIMARY + OH = OH | 9.0E-12 | ||
| <T02> | FORM_PRIMARY + NO3 = NO3 | 5.8E-16 | ||
| <T03> | FORM_PRIMARY + O = O | 3.4E-11*exp(-1600/T) | ||
| <T04> | FORM_PRIMARY = | 1.0/<HCHO_R_SAPRC99> | ||
| <T05> | FORM_PRIMARY = | 1.0/<HCHO_M_SAPRC99> | ||
| <TCL1> | FORM_PRIMARY + CL = CL | 8.2E-11*exp(-34/T) | ||
| <T06> | ALD2_PRIMARY + OH = OH | 5.6E-12*exp(270/T) | ||
| <T07> | ALD2_PRIMARY + NO3 = NO3 | 1.4E-12*exp(-1900/T) | ||
| <T08> | ALD2_PRIMARY + O = O | 1.8E-11*exp(-1100/T) | ||
| <T09> | ALD2_PRIMARY = | 1.0/<CCHO_R_SAPRC99> | ||
| <TCL2> | ALD2_PRIMARY + CL = CL | 7.9E-11 | ||
| <T10> | BUTADIENE13 + OH = OH + 0.58*ACROLEIN | 1.4E-11*exp(424./T) | ||
| <T11> | BUTADIENE13 + O3 = O3 + 0.52*ACROLEIN | 8.2E-15*exp(-2070./T) | ||
| <T12> | BUTADIENE13 + NO3 = NO3 + 0.045*ACROLEIN | 1.79E-13 | ||
| <TCL3> | BUTADIENE13 + CL = CL + 0.58*ACROLEIN | 2.51E-10 | ||
| <T14> | ACROLEIN_PRIMARY + OH = OH | 2.0E-11 | ||
| <T15> | ACROLEIN_PRIMARY + O3 = O3 | 2.61E-19 | ||
| <T16> | ACROLEIN_PRIMARY + NO3 = NO3 | 1.7E-11*exp(-3131./T) | ||
| <T17> | ACROLEIN_PRIMARY = | 1.0/<ACROLEIN_SAPRC99> | ||
| <TCL4> | ACROLEIN_PRIMARY + CL = CL | 2.37E-10 | ||
| <T18> | ACROLEIN + OH = OH | 2.0E-11 | ||
| <T19> | ACROLEIN + O3 = O3 | 2.61E-19 | ||
| <T20> | ACROLEIN + NO3 = NO3 | 1.7E-11*exp(-3131./T) | ||
| <T21> | ACROLEIN = | 1.0/<ACROLEIN_SAPRC99> | ||
| <TCL5> | ACROLEIN + CL = CL | 2.37E-10 | ||
| <T22> | TOLU + OH = OH | 1.8E-12*exp(355./T) | ||
| <TCL6> | TOLU + CL = CL | 6.1E-11 | ||
| <T23> | MXYL + OH = OH | 1.7E-11*exp(116./T) | ||
| <TCL7> | MXYL + CL = CL | 1.4E-10 | ||
| <T24> | OXYL + OH = OH | 1.22E-11 | ||
| <TCL8> | OXYL + CL = CL | 1.5E-10 | ||
| <T25> | PXYL + OH = OH | 1.3E-11 | ||
| <TCL9> | PXYL + CL = CL | 1.5E-10 | ||
| <T26> | APIN + O = O | 2.79E-11 | ||
| <T27> | APIN + OH = OH | 1.2E-11*exp(440./T) | ||
| <T28> | APIN + O3 = O3 | 6.3E-16*exp(-580./T) | ||
| <T29> | APIN + NO3 = NO3 | 1.2E-12*exp(490./T) | ||
| <TCL10> | APIN + CL = CL | 4.7E-10 | ||
| <T30> | BPIN + O = O | 2.81E-11 | ||
| <T31> | BPIN + OH = OH | 7.51E-11 | ||
| <T32> | BPIN + O3 = O3 | 1.74E-15*exp(-1260./T) | ||
| <T33> | BPIN + NO3 = NO3 | 2.81E-11 | ||
| <TCL11> | BPIN + CL = CL | 5.3E-10 | ||
| <HG1> | HG + O3 = 0.5*HGIIAER + 0.5*HGIIGAS + O3 | 2.11E-18*exp(-1256.5/T) | ||
| <HG2> | HG + CL2 = HGIIGAS + CL2 | 2.6E-18 | ||
| <HG3> | HG + H2O2 = HGIIGAS + H2O2 | 8.5E-19 | ||
| <HG4> | HG + OH = 0.5*HGIIAER + 0.5*HGIIGAS + OH | 7.7E-14 | ||
| <HG5> | HG + CL + M = 0.5*HG + 0.5*HGIIGAS + M + CL | 2.25E-33*exp(-680.0/T) |
